The phase transitions in which the entropy will increase are condensation, sublimation, and freezing. In condensation, the entropy increases as gas molecules turn into liquid molecules.
What is entropy ?Entropy is a measure of disorder in a system. It is a measure of randomness and unpredictability. Entropy is expressed as a mathematical equation that helps to quantify the amount of disorder or randomness in a system. In thermodynamics, the entropy of a system is related to the amount of energy that is unavailable for doing useful work. In information theory, entropy is a measure of the uncertainty associated with predicting the outcome of a random process. In classical mechanics, entropy is related to the number of possible states that a system can exist in.
In sublimation, the entropy increases as solid molecules turn into gas molecules. In freezing, the entropy increases as liquid molecules turn into solid molecules. Deposition does not increase entropy as the molecules remain in the same state (solid).
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The chemical equation for a reaction is shown below.
2 NO2(g) → N2O4(g)
What is the standard free energy change (ΔGo) in this reaction at 298 K? (NOTE: At 298 K, ΔGfo for NO2 is 51.84 kJ/mol, and for N2O4 is 98.28 kJ/mol.)
The standard free energy change (∆Gº') is the energy released when the products are created from the reactants. The (∆Gº') at 298 K is -5.40kJ.
What is standard free energy change?The standard free energy change is given by the sum of the standard free energies of the products subtracted from the sum of the standard free energies of the reactants, given as,
ΔG = ∑nΔG°products − ∑mΔG°reactants
Given,
ΔG°(NO₂) = 51.84 kJ/mol
ΔG°(N₂O₄) = 98.28 kJ/mol
Substituting values:
ΔG = ∑nΔG°products − ∑mΔG°reactants
= ΔG°(N₂O₄) − 2ΔG°(NO₂)
= 98.28 − 2(51.84)
= - 5.4
Therefore, -5.40 kJ is the standard free energy.
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Put the following chromatography solvent in order of polarity as a chromatography solvent: acetone, npropanol, water, hexane, diethyl ether, methanol. 2) You will be doing chromatography with a mixture of n-propanol and water. Would it make sense to add 5) Two cars full of people took a day trip. Car A had a lot of little kids and stopped at lots of rest stops and gas stations to give them a break. Car B had just adults in it, and only stopped once. Of course Car B got to the destination first. Explain how this in an analogy for the chromatography you are doing in this experiment help please
LEAST TO MOST POLAR- hexane,diethyl ether,acetone,n-propanol,water ,methanol
Considering the problem we can say that the kids are compared to be more polar or smaller molecular weight compounds. The more polar compounds interact with silica more just as the kids bus stopped at every point and reached the destination late. Whereas, the adult bus is compared to be less polar compounds or high molecular weight which interacts less and reaches the destination faster.
Thus more polar compounds reaches the destination late whereas less polar compound reaches first.
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What element is this? In my family there are non-metals, metalloids, and metals. I am commonly used in the canning business and sometimes give soup a distinct taste. I've been known to "cry" if you've bend me too hard.
The element that has in its family non-metals, metalloids, and metals, which is commonly used in the canning business and sometimes give soups a distinct taste and that is also been known to "cry" if you bend it too hard is tin.
What is tin?
Tin is a chemical element found in the periodic table with atomic number 50 and which has the symbol Sn.
The characteristics of tin include:
Tin is a silver-colored metal.Tin is a soft metal such that it can be cut even when little force is appliedPure solid tin has a shiny lustrous appearance as is similar to most metals.Because of its high resistance to corrosion and soft nature, tin has been used for a wide variety of purposes which include:
it is used in the electroplating of steel cans used as food containers,it is used together with other metals in producing bearingsIt is used in soldering worksLearn more about tin at: https://brainly.com/question/2272323
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when a h atom absorbs an ultraviolet photon with the correct energy, what transition can the electron in the atom undergo?
When an H atom absorbs an ultraviolet photon with the correct energy, the electron in the atom can undergo a transition from the fifth energy level (n=5) to the first energy level (n=1).
This type of transition is called a "quantum jump" and is associated with the emission of a photon. When an H atom absorbs an ultraviolet photon with the correct energy, it will move from its ground state to an excited state.
This excitation of the electron can then lead to further processes such as the emission of a photon or the formation of an ion-pair. Therefore the correct answer is D)n=5 to n=1 when the H atom absorbs an ultraviolet photon with the correct energy
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complete question:
when a H atom absorbs an ultraviolet photon with the correct energy, what transition can the electron in the atom undergo?
A)n=1 to n=5
B)n=2 to n=6
C)n=6 to n=2
D)n=5 to n=1
How many grams is 6.57E24 molecules of N2O4 gas at STP?
6.57E24 molecules of N2O4 gas at STP will have a mass of 1001.77 g.
What is STP?Standard Temperature and Pressure are referred to as STP. The physical and chemical characteristics of gases are defined by this common set of circumstances. The temperature and pressure are defined as 0°C or 273.15 K and 1 atm (atmosphere), respectively, at STP (kilopascals). By using these conditions as a baseline, it is possible to compare the volume, pressure, and other characteristics of gases. Many calculations involving gases use the 22.4 L/mol molar volume of an ideal gas at STP as a conversion factor. STP is frequently used in computations and lab experiments in disciplines including engineering, physics, and chemistry. It's essential to compare different data sets in a meaningful way.
The molar mass of N2O4 can be calculated as follows:
Molar mass of N2O4 = 2(N) + 4(O)
Molar mass of N2O4 = 2(14.007 g/mol) + 4(15.999 g/mol)
Molar mass of N2O4 = 92.011 g/mol
Convert molecules to moles:
6.57E24 molecules of N2O4 can be converted to moles by dividing by Avogadro's number, which is 6.022E23 mol^-1:
6.57E24 molecules / 6.022E23 mol^-1 = 10.89 moles
At STP (standard temperature and pressure), the conditions are:
Temperature (T) = 273.15 K
Pressure (P) = 1 atm
Volume (V) = 22.4 L/mol (molar volume of an ideal gas at STP)
We can use the ideal gas law to calculate the mass of the gas:
PV = nRT
where:
P = pressure (1 atm)
V = volume (22.4 L/mol)
n = moles (10.89 mol)
R = gas constant (0.08206 L atm K^-1 mol^-1)
T = temperature (273.15 K)
Solving for mass (m):
m = n x Molar mass
m = 10.89 mol x 92.011 g/mol
m = 1001.77 g
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How much heat would be required to heat 10 grams of liquid water from 50 ºc to vapor at 100 ºc? report your answer in kj to one decimal place.
Heat would be required to heat 10 grams of liquid water from 50 ºC to vapor at 100 ºC is 2.09 kJ.
Given that :
mass = 100 g
initial temperature = 50 ºC
final temperature = 100 ºC
specific heat capacity is 4.18 J/g ºC
The heat expression is given as :
Q = mc ΔT
where,
Q = heat
m = mass
ΔT = change in temperature
Q = 10 g × 4.18 J /g °C × ( 100 °C - 50 °C )
Q = 41.8 J /°C × 50 °C
Q = 2090 J
Q = 2.09 kJ
Thus, Heat would be required to heat 10 grams of liquid water from 50 ºC to vapor at 100 ºC is 2.09 kJ.
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If velocity is positive, which would most likely yield a negative acceleration?
A final velocity that is faster than an initial velocity.
A time that is less than a half hour.
An initial velocity that is faster than a final velocity.
A time that is greater than a half hour.
Answer:
C. An intitial velocity that is faster than a final velocity.
Explanation:
taking the test rn but it makes sense because you'd have to slow down to get a lesser final velocity.
Answer:
C
Explanation:
Propane gas (C3H8) is ignited. Type of reaction ________ ignition ___________________ Balanced chemical equation:
Propane gas (C3H8) is ignited. Type of reaction combustion ignition.
\(C_3H_8(g)+5O_2(g) < = > 3CO_2(g)+4H_2O(l)\) Balanced chemical equation.
A balanced chemical reaction is what?A chemical equation is said to be balanced if the quantity of each type of atom in the reaction is the same on both the reactant and product sides. In a balanced chemical equation, the mass and the change are both equal.
Propene is an alkene because why?The parent chain is the longest chain of carbon atoms that contains the double bond. Its name has the same stem as an alkane with the same number of carbon atoms, but it is designated as an alkene by adding the suffix -ene. Propene is the resultant chemical, CH2=CHCH3.
What does a balanced chemical equation entail?In accordance with the Law of Conservation of Mass, mass cannot be generated or destroyed in a chemical reaction. A balanced chemical equation has an equal number of atoms of each element on the left and right sides of the reaction.
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How do organisms get energy from their environment?
Answer: They either eat other organisms or plants they take in the sun and water.
If you want to compare the quantity of chromium produced to the quantity of aluminum and silicon required for the process, what units would be best to use? Choose one: A grams B. grams per cm^3 C. atoms D. moles
If you want to compare the quantity of chromium produced to the quantity of aluminum and silicon required for the process, Moles units would be best to use.
A mole is defined as 6.02214076 × \(10^{23}\) of some chemical unit, be it atoms, molecules, ions, or others. The mole is a convenient unit to use because of the great number of atoms, molecules, or others in any substance. The number of moles can be identified by dividing the given mass by molar mass.
The number of moles of a substance can be calculated using the following formula: Mole= Mass ÷Mr
The Mr of a compound is its molecular weight, which is the sum of the relative atomic masses of the atoms it is made up of. One mole of aluminium atoms has a mass of 27 grams.
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How many liters of carbon dioxide gas are there in 4 moles of CO2 at STP?
Answer:
89.6 L
Explanation:
In normal conditions,
For every 1 mole of carbon dioxide at STP, it occupies 22.4 L of volume.
============================================================
Solving :
⇒ 1 mole : 22.4 L
⇒ 1 × 4 : 22.4 × 4
⇒ 4 moles : 89.6 L
Scientific method quick check
Answer:
Quick you said:
-Purpose/Question
Ask a question.
-Research
Conduct background research. Write down your sources so you can cite your references. In the modern era, a lot of your research may be conducted online. Scroll to the bottom of articles to check the references. Even if you can't access the full text of a published article, you can usually view the abstract to see the summary of other experiments. Interview experts on a topic. The more you know about a subject, the easier it will be to conduct your investigation.
-Hypothesis
Propose a hypothesis. This is a sort of educated guess about what you expect. It is a statement used to predict the outcome of an experiment. Usually, a hypothesis is written in terms of cause and effect. Alternatively, it may describe the relationship between two phenomena. One type of hypothesis is the null hypothesis or the no-difference hypothesis. This is an easy type of hypothesis to test because it assumes changing a variable will have no effect on the outcome. In reality, you probably expect a change but rejecting a hypothesis may be more useful than accepting one.
-Experiment
Design and perform an experiment to test your hypothesis. An experiment has an independent and dependent variable. You change or control the independent variable and record the effect it has on the dependent variable. It's important to change only one variable for an experiment rather than try to combine the effects of variables in an experiment. For example, if you want to test the effects of light intensity and fertilizer concentration on the growth rate of a plant, you're really looking at two separate experiments.
-Data/Analysis
Record observations and analyze the meaning of the data. Often, you'll prepare a table or graph of the data. Don't throw out data points you think are bad or that don't support your predictions. Some of the most incredible discoveries in science were made because the data looked wrong! Once you have the data, you may need to perform a mathematical analysis to support or refute your hypothesis.
-Conclusion
Conclude whether to accept or reject your hypothesis. There is no right or wrong outcome to an experiment, so either result is fine. Accepting a hypothesis does not necessarily mean it's correct! Sometimes repeating an experiment may give a different result. In other cases, a hypothesis may predict an outcome, yet you might draw an incorrect conclusion. Communicate your results. The results may be compiled into a lab report or formally submitted as a paper. Whether you accept or reject the hypothesis, you likely learned something about the subject and may wish to revise the original hypothesis or form a new one for a future experiment.
A sample of ideal gas at room temperature occupies a volume of 28.0 L at a pressure of 882 torr. If the pressurechanges to 4410 torr , with no change in the temperature or moles of gas, what is the new volume, V?Express your answer with the appropriate units.
To solve this problem, we could use the Boyle's law since there's a sample of ideal gas and temperature is constant.
Boyle's law tells us that:
Replacing the values of the problem:
The new volume V equals 5.6L.
contrast resting potential, hyperpolarization, depolarization, threshold potential, and the action potential in neurons what are ions?
Ions are electrically charged molecules that play an important role in the functioning of neurons.
Here, correct answer will be
They are present in the intracellular and extracellular fluid surrounding neurons, and their movements across the cell membrane are responsible for changes in the electrical potential of a neuron. The resting potential of a neuron is the electrical charge of a neuron when it is not actively sending signals, and is maintained by the movement of ions across the cell membrane.
Hyperpolarization occurs when the electrical charge of the neuron is increased, and depolarization when the electrical charge is decreased. The threshold potential is the electrical charge required for the neuron to generate an action potential, which is an electrical impulse or "spike" that is sent down the neuron's axon.
The action potential is generated by the rapid movement of ions across the cell membrane, creating an electrical impulse that is then transmitted to other neurons.
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when the amount of energy increases, what happens to the frequency of that wave?
A sample of gas has a volume of 526 mL at 346 mmHg and 35.0°C. Determine the moles of gas.
Answer:
The moles of gas is 0.009474 moles.
Explanation:
Given that,
Volume = 526 mL
Pressure = 346 mmHg
Temperature = 35.0°C
We need to calculate the moles of gas
Using formula of ideal gas
\(n=\dfrac{PV}{RT}\)
Where, P = pressure
V = volume
R = gas constant
T = temperature
Put the value into the formula
\(n=\dfrac{\dfrac{346}{760}\times0.526}{0.08206\times(35+273)}\)
\(n=0.009474\ moles\)
Hence, The moles of gas is 0.009474 moles.
Which of the following correctly pairs a phase of
matter with its description?
A Solid: Particles have no motion.
B Liquid: Particles expand to fill any container in
which they are placed.
C Gas: Particles have higher amounts of energy
than when in the liquid phase.
D Liquid: Particles are more strongly attached to
one another than when in the solid phase.
PLEASE ANSWER
The option that correctly pairs a phase of matter with its description is :
( C ) Gas: particles have higher amounts of energy than when in the liquid phase
Characteristics of GasGases are composed of losely parked molecules which are easily compressed into a container. Gases take the shape and the volume of the container in which they are put in, also gas molecules are the most mobile therefore they posses higher amounts of energy.
Hence we can conclude that Gas: particles have higher amounts of energy than when in the liquid phase.
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Why do we round numbers?
Answer:
We round numbers so we can find an answer or an estimate that will be close to the actual answer. Rounding numbers is also another way to get close to an exact answer without the trouble of having to calculate every number.
Answer:
Rounding numbers make the numbers easier and more simple to use . Though they may less accurate because of the changes number . Rounding is mainly used for estimates
11.All of the following properties of a diamond are physical except...Select one:a. It does not conduct electricity.b. It produces carbon dioxide when burned in pure oxygen.c. It is transparent like glass.d. It is the hardest material.
Answer
b. It produces carbon dioxide when burned in pure oxygen.
Explanation
The reaction between diamond and oxygen, producing carbon dioxide is not a physical property of diamond, it is a chemical property because breaking and synthesis of chemical bonds occur.
Explain how the Celsius scale was devised and why it is not appropriate to use when describing the behavior of gases // please help ?!
The freezing point, boiling point, or any combination of water and a chemical were all used as the basis for the Celsius and Fahrenheit scales.
Characteristic of Absolute temperature scale:-Scientists adopted the Kelvin temperature scale because they desired a scale where 0 depicts the total lack of thermal energy.The connection between pressure and Tc is NOT PROPORTIONAL (the graph of pressure vs. T (°C) does not run through the origin - pressure is not zero at 0 °C), hence using the Celsius scale to describe the behavior of gases is not suitable.) Volume and Tc are not proportionate, either. Temperature calculations must be done on an absolute scale in order for gas laws to function. On the other hand, the zero point in Celsius is arbitrary and represents the temperature at which water melts. Another issue with Celsius is the high likelihood of negative degrees, which can lead to unclear findings.Learn more about the Absolute temperature scale with the help of the given link:
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Sedimentary rock:
1. has large crystals
2. forms in layers
3. is formed from pressure and heat
4. cools slowly
Answer:
Option 2: Forms in layers.
Answer:
2. Sedimentary rock forms in layers. Under the water eg sea water, river etc the grains and sand form together and that makes them in layers
Write the formulas for the methylmercury
ion, for two of its common molecular forms, and for dimethylmercury. What is the principal source of exposure of humans to methylmercury?
The formulas for methylmercury ion and two of its common molecular forms are CH₃Hg⁺, CH₃HgCl, and (CH₃)²Hg. The principal source of exposure of humans to methylmercury is contaminated seafood.
The formula for the methylmercury ion is CH₃Hg⁺. It consists of a methyl group (CH₃) attached to a mercury ion (Hg+). Methylmercury can also form various molecular forms depending on its interaction with other compounds. One common form is methylmercury chloride (CH₃HgCl), where a chloride ion (Cl-) replaces one of the hydrogen atoms in the methylmercury ion. Another form is dimethylmercury ((CH₃)²Hg), which contains two methyl groups attached to a mercury atom.
The principal source of human exposure to methylmercury is the consumption of contaminated seafood. Methylmercury is produced in aquatic environments through microbial transformations of inorganic mercury. It biomagnifies through the food chain, accumulating in higher levels in predatory fish and marine mammals. When humans consume contaminated seafood, particularly large predatory fish like shark, swordfish, and king mackerel, ingestion they can be exposed to methylmercury. This exposure poses health risks as methylmercury is a potent neurotoxin that can affect the central nervous system, especially in developing fetuses and young children. Therefore, it is important to be aware of the potential sources of methylmercury and make informed choices regarding seafood consumption.
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Which of the following correctly identifies an acid-base pair?
HCl, NaOH
H2CO3 , CO32-
H3O+ , OH-
NH3, NH4+
An acid-base pair is correctly identified by HCl, and NaOH.
The acid and the base that make up an acid-base pair are called the conjugate acid-base pair. The acid is a proton (H+) donor, whereas the base is a proton (H+) acceptor. In general, the base is a molecule that is not a hydrogen ion (H+) or a hydronium ion (H3O+).
The acid, on the other hand, is the molecule that donates a proton. In the reaction, the base is transformed into an acid, and the acid is transformed into a base.HCl and NaOH can be identified as an acid-base pair since NaOH is the base, and HCl is the acid. HCl is a hydrogen chloride acid, and NaOH is a sodium hydroxide base.
In the chemical reaction of HCl and NaOH, the acid and the base react to form a neutral compound, which is salt and water, according to the reaction HCl + NaOH → NaCl + H2O.H2CO3 and CO32- are not a correct acid-base pair because both are anions (ions with a negative charge).H3O+ and OH- are the correct acid-base pair because H3O+ (hydronium ion) is an acid, and OH- (hydroxide ion) is a base.
However, the question asks for the correct pair of acids and bases.NH3 and NH4+ are not correct acid-base pairs because both are bases. The acid NH3 and the base NH4+ are conjugate pairs, according to the reaction NH3 + H+ → NH4+.
Therefore, the correct answer is HCl, and NaOH since they represent an acid-base pair.
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Suppose a woman aged 53 years old has a serum-estradiol measurement of 13.5 pg/mL. Given an overall cancer prevalence of 2% and using the cutpoint of ≥ 20 pg/mL to define a positive test, what is the probability that she does NOT have cancer?
The probability that the woman does not have cancer is approximately 98.53%.
Calculate the probability of having cancer given a positive test result.
Given an overall cancer prevalence of 2%, we can assume that the probability of having cancer is 0.02. To calculate the probability of having a positive test result, we need to determine the false positive rate (1 - specificity) of the test. The specificity of the test can be calculated by subtracting the false positive rate from 1. However, the false positive rate is not provided in the given information, so we cannot calculate the exact specificity of the test. Therefore, we cannot determine the probability of having cancer given a positive test result.
Calculate the probability of not having cancer given a negative test result.
To calculate the probability of not having cancer given a negative test result, we need to determine the false negative rate (1 - sensitivity) of the test. The sensitivity of the test can be calculated by subtracting the false negative rate from 1. Again, the false negative rate is not provided, so we cannot calculate the exact sensitivity of the test. However, since we know the cutpoint for defining a positive test result is ≥ 20 pg/mL, and the woman's serum-estradiol measurement is 13.5 pg/mL, which is below the cutpoint, we can assume that she would have a negative test result. Therefore, the probability of not having cancer given a negative test result would be close to 100%.
Calculate the probability that she does not have cancer.
The probability that she does not have cancer can be approximated by multiplying the probability of not having cancer given a negative test result with the probability of having a negative test result. Assuming the sensitivity and specificity of the test are reasonably high, we can estimate that the probability of not having cancer given a negative test result is close to 100%, and the probability of having a negative test result is close to 100%. Therefore, the probability that she does not have cancer is approximately 98.53%.
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What is the balanced net ionic equation of mixed AgNO3 and MgCl2 solutions?
A. Ag+(aq) + Cl–(aq) → AgCl(s)
B. Ag+(aq) + Cl2–(aq) → AgCl2(s)
C. Mg2+(aq) + NO3–(aq) → Mg(NO3)2(s)
D. Ag3+(aq) + 3Cl–(aq) → AgCl3(s)
Answer:
The balanced net ionic equation of mixed AgNO3 and MgCl2 solutions is Mg2+(aq) + 2Cl–(aq) → MgCl2(s). AgNO3 and MgCl2 are both ionic compounds and the reaction is a double replacement reaction. AgNO3 is composed of silver ions (Ag+) and nitrate ions (NO3–) while MgCl2 is composed of magnesium ions (Mg2+) and chloride ions (Cl–). When these two compounds are mixed together, the silver and nitrate ions react with the magnesium and chloride ions to form the silver chloride (AgCl) and magnesium chloride (MgCl2) products.
an experiment determines that 29.64 ml of 0.107 m naoh completely neutralizes a beaker containing 71 ml h2so4. what is the molarity of h2so4
The molarity of the H₂SO₄, given that 29.64 mL of 0.107 M NaOH completely neutralizes 71 mL of H₂SO₄, is 0.022 M
How do I determine the molarity of the H₂SO₄?The balanced equation for the reaction is given below:
H₂SO₄ + 2NaOH —> Na₂SO₄ + 2H₂O
The mole ratio of the acid, H₂SO₄ (nA) = 1The mole ratio of the base, NaOH (nB) = 2We shall determine the molarity of the H₂SO₄ solution as illustrated below:
Volume of NaOH (Vb) = 29.64 mLMolarity of NaOH (Mb) = 0.107 M Volume of H₂SO₄ (Va) = 71 mLMolarity of H₂SO₄ (Ma) =?MaVa / MbVb = nA / nB
(Ma × 71) / (0.107 × 29.64) = 1 / 2
Cross multiply
Ma × 71 × 2 = 0.107 × 29.64 × 1
Divide both side by (71 × 2)
Ma = (0.107 × 29.64 × 1) / (71 × 2)
Ma = 0.022 M
Thus, we can conclude that the molarity of the H₂SO₄ is 0.022 M
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FILL IN THE BLANK An electrolytic capacitor is often used to store ____ at ____.
An electrolytic capacitor is often used to store large amount of charge at low voltages.
A capacitor stores electrical energy by distributing charged particles on two plates to generate a potential difference.
Electrolytic capacitors are better than batteries as they can be charged or discharged at a very rapid rate. This is because the electrolytic capacitors have very low resistance.
Electrolytic capacitors are also called as polarized capacitor, that is the voltage applied to the terminals must have the right polarity.
The electrical conductivity of the capacitor increases with increase in temperature and decreases with decrease in temperature.
Therefore, an electrolytic capacitor is often used to store large amount of charge at low voltages.
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A scientist heats a 300-g sample of iron from 30°C to 50°C. How much heat did the iron absorb.
The specific heat capacity of iron is 0.45 J/gºC.
Оа
Oь
Ос
Od
3,000)
2,700)
202,500)
2,500)
Answer:
d
Explanation:educated guess
Which of these is made up of cells and tissues that perform a larger function? Group of answer choices Atom Compound Molecule Organ
Answer:
compound
Explanation:
because it is made up of pure substance consists of atom
Answer:
Organ
Explanation:
I got it right when I took the test.
(14 points) 354 ml of a stock solution of nh4cl was added to 2.0 l of water. if the final ph was 5.43, what was the concentration of the stock solution (in m)?
The concentration of the stock solution was 0.474 M. The first step is to determine the moles of NH4Cl that were added to the water:
moles of NH4Cl = (volume of stock solution in liters) x (Molarity of stock solution)
moles of NH4Cl = (0.354 L) x (Molarity)
Next, we need to calculate the concentration of the NH4+ ions in the solution:
[NH4+] = moles of NH4Cl / total solution volume
[NH4+] = moles of NH4Cl / (2.0 L + 0.354 L)
[NH4+] = moles of NH4Cl / 2.354 L
Since NH4Cl dissociates into NH4+ and Cl- in water, we also need to take into account the dissociation reaction and the acid-base equilibrium that occurs between NH4+ and H2O:
NH4+ + H2O ⇌ NH3 + H3O+
The acid dissociation constant (Ka) for this reaction is 5.6 x 10^-10 at 25°C. At pH 5.43, the concentration of H3O+ ions can be calculated using the equation:
pH = -log[H3O+]
[H3O+] = 10^-pH
[H3O+] = 10^-5.43
[H3O+] = 2.24 x 10^-6 M
Using the equilibrium constant expression for the acid-base reaction, we can write:
Ka = [NH3][H3O+] / [NH4+]
Since the concentration of NH3 is equal to the concentration of NH4+ (since they are in a 1:1 ratio), we can substitute [NH4+] for [NH3]:
Ka = [NH4+][H3O+] / [NH4+]
Simplifying:
Ka = [H3O+]
Substituting the value of Ka and [H3O+]:
5.6 x 10^-10 = 2.24 x 10^-6
[NH4+] = [NH3] = √(Ka/[H3O+])
[NH4+] = [NH3] = √(5.6 x 10^-10 / 2.24 x 10^-6)
[NH4+] = [NH3] = 0.0089 M
Finally, we can use the fact that NH4Cl dissociates into one NH4+ ion and one Cl- ion to calculate the molarity of the stock solution:
0.0089 M = (mass of NH4Cl / volume of stock solution in liters) / 2
The mass of NH4Cl can be calculated from its molar mass (53.49 g/mol) and the volume of the stock solution:
mass of NH4Cl = molarity x volume x molar mass
mass of NH4Cl = 0.0089 M x 0.354 L x 53.49 g/mol
mass of NH4Cl = 0.168 g
Therefore, the concentration of the stock solution is:
0.168 g / 0.354 L = 0.474 M
So the concentration of the stock solution was 0.474 M.
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